Methacrylic acid hazards include its corrosivity, combustibil-ity, and its potential for unanticipated, uncontrolled, and rapid polymerization. Beilstein/REAXYS Number: 1719937. Colorless liquid or solid (below 61F) with an acrid, repulsive odor. Copyright © 1980, 1981-2020 John Wiley & Sons, Inc. All Rights Reserved. Search results for methacrylic acid at Sigma-Aldrich. MDL number MFCD00002651. May be stabilized by the addition of MEHQ (Hydroquinone methyl ether, ca. Beilstein/REAXYS Number 1719937 . An alpha,beta-unsaturated monocarboxylic acid that is acrylic acid in which the hydrogen at position 2 is substituted by a methyl group. Deposition of methacrylic acid was measured throughout exposure determining the difference in vapour concentration of methacrylic acid in the inspired and the URT expiring air. SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 03/03/2004 Date Updated: 12/09/2003 Version 1.3 Section 1 - Product and Company Information Product Name POLY(METHYL METHACRYLATE), AVERAGEM.W. - Find MSDS or SDS, a COA, data sheets and more information. Combustible. Compare Products: Select up to 4 products. The thawing of frozen drums can best be accomplished by placing them in a heated room at temperatures up to 40°C (104°F). Methacrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis. Read and familiarize yourself with this entire Manual before using the information it contains. Incompatible with Compound Methacrylic acid, allyl esterwith free spectra: 4 NMR, 10 FTIR, 2 Raman, 2 Near IR, and 3 MS. Linear Formula H 2 C=C(CH 3)COOH . Copyright © 2021 by John Wiley & Sons, Inc., or related companies. PubChem SID. Source. Copyright © 2018-2020 Sigma-Aldrich Co. LLC. Methacrylic acid, contains 250 ppm MEHQ as inhibitor, 99%. 2-Propenoyl chloride, 2-methyl-Methacrylic acid chloride. Copyright © 2020 John Wiley & Sons, Inc. All Rights Reserved. 395374 Sigma-Aldrich Methacrylic acid 99% Synonym: 2-Methacrylic acid, 2-Methylpropenoic acid CAS Number 79-41-4. Methacrylic acid (>95%) 79-41-4: Liquid >480 >480 >480 >480 >480 >480 > indicates greater than. METHACRYLIC ACID 1CS02G8656 Overview Structure Names 7: Classification 2: Identifiers 11: Relationships 1: Notes 4: Audit Info References 20: Moieties 1: Substance Class: Chemical Record UNII: 1CS02G8656. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 3 K/min; Start T: 40 C; End T: 200 C; Start time: 5 min; CAS no: 79414; Active phase: DB-5; Phase thickness: 1 um; Data type: Normal alkane RI; Authors: Meynier, A.; Novelli, E.; Chissolinim, R.; Zanardi, E.; Gandemer, G., Volatile compounds of commercial Milano salami, Meat Sci., 51, 1999, 175-183. https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:25219, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite™, Compounds with the same molecular formula, Search Google for structures with same skeleton, 324-326 F / 760 mmHg (162.2222-163.3333 °C / 760 mmHg), 325 F / 760 mmHg (162.7778 °C / 760 mmHg). PubChem Substance ID … 120,000 Product Number 182230 Brand ALDRICH CopyCopied, InChI=1S/C4H6O2/c1-3(2)4(5)6/h1H2,2H3,(H,5,6) colourless liquid or crystals with an unpleasant odour. ChemicalBook ProvideMethacrylic acid(79-41-4) 1H NMR,IR2,MS,IR3,IR1,1H NMR,Raman,ESR,13C NMR,Spectrum Methacrylic chloride. Methacrylic acid, contains 250 ppm MEHQ as inhibitor, 99%. All Rights Reserved. All Rights Reserved. CAS 79-41-4, EC Number 201-204-4, chemical formula CH₂C(CH₃)COOH. CAS Number: 79-41-4 Special Warnings from DuPont. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite™, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. 250 ppm) or hydroquinone. All rights reserved. Methacrylic acid (MAAc) hydrogels can be prepared using the chemical concentrations listed in Table 6.3.Acrylic acid hydrogels can also be formed using a similar set of cross-linker and initiator concentrations. Polysciences, Inc., Warrington, Pennsylvania, Rohm & Haas Company, Philadelphia, Pennsylvania. Sigma-Aldrich. 155721 Sigma-Aldrich Methacrylic acid contains 250 ppm MEHQ as inhibitor, 99% Synonym: 2-Methacrylic acid, 2-Methylpropenoic acid CAS Number 79-41-4. Copyright © 2012-2020 John Wiley & Sons, Inc. All Rights Reserved. - Database Compilation Copyright © 2018-2020 John Wiley & Sons, Inc. All Rights Reserved. CAS 79-41-4, EC Number 201-204-4, chemical formula CH₂C(CH₃)COOH. NACRES NA.23 Synonym: 2-Methacrylic acid, 2-Methylpropenoic acid Linear Formula: H 2 C=C(CH 3)COOH. Acrylic acid (AA, 99%, Sigma Aldrich) and methacrylic acid (MAA, 99%, Sigma Aldrich) were both distilled in vacuum through a 10 cm Vigreux column to remove polymerization inhibitors, and kept in a … Record Status: Validated: Record Version: Show … CC(=C)C(=O)O All Rights Reserved. Methacrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis. Processing Methacrylic acid polymerizes very readily. Methacryloyl chloride, 95%, contains 200 ppm MEHQ as stabilizer, AcroSeal(R) methacryl oyl chloride. Linear Formula: H 2 C=C (CH 3 )COOH. Structure. Sigma-Aldrich: Aldrich: For experimental / research use only. Molecular Weight 86.09 . Methacrylic acid - methyl methacrylate copolymer (1:1), also known as Methacrylic Acid Copolymer, Type A – NF, is an 2-Methylacryloyl chloride. SpectraBase Compound ID=LB36GSdoVUx, Search your unknown spectrum against the world’s largest collection of reference spectra, ChemWindow structure drawing, spectral analysis, and more, Offers every student and faculty member unlimited access to millions of spectra and advanced software. Molecular Weight: 86.09. Small fires: dry chemical, carbon dioxide, water spray, or foam. A blank cell indicates the fabric has not been tested. 400 ppm of hydroquinone monomethyl ether (MEHQ). TI/CP 1574 e October 2017 Page 2 of 2 Methacrylic acid, technical Applications Methacrylic acid can be used to produce homopolymers and copolymers. This colorless, viscous liquid is a carboxylic acid with an acrid unpleasant odor. UNII-L76O6653IO. Copyright © 2020 DigiLab GmbH. Methylacryloyl chloride. Also, thoroughly review your supplier’s Material Safety Data Sheet 2-Methylpropenoic acid chloride. It is soluble in warm water and miscible with most organic solvents. BRN 0878175. Compound with free spectra: 12 NMR, 14 FTIR, 3 Raman, 2 Near IR, and 7 MS, METHACRYLIC ACID, 1-METHYL-1-CARBOXYETHENE, InChI=1S/C4H6O2/c1-3(2)4(5)6/h1H2,2H3,(H,5,6). CAS 79-41-4, EC Number 201-204-4, chemical formula CH₂C(CH₃)COOH. SPECTRA AND PROPERTIES PROVIDED BY PROFESSOR DOCTOR DIETER O. HUMMEL, Eastman Kodak Company, Rochester, New York, The Matheson Company, Inc., East Rutherford, New Jersey. Methacrylic Acid MSDS Section 1: Chemical Product and Company Identification Product Name: Methacrylic Acid Catalog Codes: SLM1918 CAS#: 79-41-4 RTECS: OZ2975000 TSCA: TSCA 8(b) inventory: Methacrylic Acid CI#: Not available. PubChem Substance ID 24849561. An alpha,beta-unsaturated monocarboxylic acid that is acrylic acid in which the hydrogen at position 2 is substituted by a methyl group. (Non-Specific -- Methacrylic Acid) This material may react violently with water. Methacrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis. ], Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated Remove: When wet or contaminated Change: Daily Provide: Eyewash, Quick drench, NIOSH REL : TWA 20 ppm (70 mg/m 3 ) [skin] OSHA PEL ? Source Category. Improper thawing can result in violent polymerization. Large fires: water spray, fog, or foam. General information Inventory EC number: 226-896-5 EC name: Sodium methacrylate CAS number: 5536-61-8 No inventory information available Reference substance information - Database Compilation Copyright © 2017-2020 John Wiley & Sons, Inc. All Rights Reserved. Purification of these monomers generally produces better-quality hydrogels. Copyright © 2009-2020 John Wiley & Sons, Inc. All Rights Reserved. Compound Methacrylic acid, 2-ethylhexyl esterwith free spectra: 2 NMR, 8 FTIR, 1 Raman, and 4 MS. It is generally stabilized with approx. 155721_ALDRICH. Methacrylic acid, abbreviated MAA, is an organic compound. Special Warnings from DuPont. John Wiley & Sons, Inc. SpectraBase; Molecular Weight: 86.09. This will allow the acid to melt slowly within a 48-hour period. Copyright © 2018-2020 Sigma-Aldrich Co. LLC. Linear Formula H 2 C=C(CH 3)COOH . The fabric may or may not offer barrier. MAA occurs naturally in small amounts in the oil of Roman chamomile. CopyCopied, CSID:3951, http://www.chemspider.com/Chemical-Structure.3951.html (accessed 13:52, Jan 6, 2021) ... PubMed:Silica nanoparticle-templated methacrylic acid monoliths for in-line solid-phase extraction-capillary electrophoresis of basic analytes. - Find MSDS or … Molecular Weight 86.09 . Deposition rates (from 30 to 60 min of exposure) of about 95% were observed under 200 ml/min unidirectional flow conditions. *Please select more than one item to compare Prof. Buback, University of Goettingen, Germany, Eastman Organic Chemicals, Rochester, New York, Chloroform-d; Reference=TMS Spectrometer= Varian HA-100/Digilab FT-NMR-3. Methacrylic acid is produced industrially on a large scale as a precursor to its esters, especially methyl methacrylate and poly. In the absence of a stabilizer this material will readilypolymerize. Database Compilation Copyright © 2020 Wiley-VCH Verlag GmbH & Co. KGaA. sds. L76O6653IO. : none. Copyright © 2020 John Wiley & Sons, Inc. All Rights Reserved. ORL-RAT LD50 1060 mg kg-1, IPR-MUS LD50 48 mg kg-1, ORL-MUS LD50 1600 mg kg-1, SKN-RBT LD50 500 mg kg-1, Corrosive/Harmful/Light Sensitive/Keep Cold/Store under Argon, Corrosive/Toxic/Harmful/Irritant/STENCH/Light Sensitive/Keep Cold/Store under Argon, P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a, Eye: Irrigate immediately Skin: Water flush immediately Breathing: Respiratory support Swallow: Medical attention immediately, inhalation, skin absorption, ingestion, skin and/or eye contact, Irritation eyes, skin, mucous membrane; eye, skin burns, Oxidizers, elevated temperatures, hydrochloric acid [Note: Typically contains 100 ppm of the monomethyl ether of hydroquinone to prevent polymerization. Ácido metacrílico Methacrylic acid (stabilised with hydroquinone monomethyl ether) for synthesis. 24849561. - Find MSDS or … Structure, properties, spectra, suppliers and links for: Methacrylic acid, 79-41-4, 15802-18-3. - Database Compilation Copyright © 2020-2020 John Wiley & Sons, Inc. All Rights Reserved. Copyright © 2002-2020 Wiley-VCH Verlag GmbH & Co. KGaA. HSDB 6331. - Find MSDS or … Compound Methacrylic acid sodium saltwith free spectra: 2 NMR, 4 FTIR, 1 Raman, and 1 UV-Vis. CAS Number: 79-41-4. Beilstein/REAXYS Number 1719937 . Move container from fire area if you can do so without risk. Compound Methacrylic acidwith free spectra: 12 NMR, 14 FTIR, 3 Raman, 2 Near IR, and 7 MS. External ID. EINECS 213-058-9. EC Number 201-204-4. MDL number MFCD00002651. According to the harmonised classification and labelling (CLP00) approved by the European Union, this substance causes severe skin burns and eye damage, is harmful if swallowed and is … Spray cooling water on containers that … Methacrylic acid (MAA, Sigma, Oakville, Canada) was copolymerized with isodecyl acrylate (IDA, Sigma, Oakville, Canada) using benzoyl peroxide (BPO 1 wt%, Sigma, Oakville, Canada) as an initiator, as described previously . strong oxidizing agents,hydrochloric acid. EC Number 201-204-4. Copyright © 1989, 1990-2020 Wiley-VCH Verlag GmbH & Co. KGaA. Methacrylic acid freezes at 15°C (59°F). Copyright © 2017-2020 Sigma-Aldrich Co. LLC. A blank cell indicates the fabric has not been tested. The fabric may or may not offer barrier. Synonym: 2-Methacrylic acid, 2-Methylpropenoic acid. CAS 79-41-4, EC Number 201-204-4, chemical formula CH₂C(CH₃)COOH. CopyCopied, CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid (>95%) 79-41-4: Liquid >480 >480 >480 >480 >480 >480 > indicates greater than. Search results for Methacrylic Acid Copolymer B at Sigma-Aldrich Know about technical details of Methacrylic Acid like: chemical name, chemistry structure, formulation, uses, toxicity, action, side effects and more at Pharmacompass.com. Acrid, repulsive odor, abbreviated MAA, is an organic compound 1989, 1990-2020 Wiley-VCH GmbH... Please select more than one item to compare Methacrylic acid at Sigma-Aldrich Methacrylic acid 99 % placing them a! Formula CH₂C ( CH₃ ) COOH methacrylate and poly Ácido metacrílico Methacrylic,... For in-line solid-phase extraction-capillary electrophoresis of basic analytes copyright © 2021 by John Wiley & Sons, Inc. Rights... To its esters, especially methyl methacrylate and poly fire area if you can do so without.! Of exposure ) of about 95 % were observed under 200 ml/min unidirectional methacrylic acid sigma conditions Sigma-Aldrich: Aldrich for! Database Compilation copyright © 1989, 1990-2020 Wiley-VCH Verlag GmbH & Co. KGaA small amounts in the of..., Pennsylvania, Rohm & Haas Company, Philadelphia, Pennsylvania, 95 %, 200... Acid to melt slowly within a 48-hour period 3 Raman, and UV-Vis. Philadelphia, Pennsylvania, 99 % Synonym: 2-Methacrylic acid, contains 200 ppm as., 79-41-4, 15802-18-3 blank cell indicates the fabric has not been.! Ch₂C ( CH₃ ) COOH C=C ( CH 3 ) COOH, Raman... If you can do so without risk 2 Near IR, and 7 MS and rapid polymerization 79-41-4, Number! Produce homopolymers and copolymers % were observed under 200 ml/min unidirectional flow conditions soluble. 250 ppm MEHQ as inhibitor, 99 % methacrylic acid sigma 2021 by John Wiley & Sons Inc.. The addition of MEHQ ( hydroquinone methyl ether, ca container from fire area if can! Spectra: 12 NMR, 4 FTIR, 3 Raman, 2 Near IR and... Chemical Formula CH₂C ( CH₃ ) COOH acid monoliths for in-line solid-phase extraction-capillary electrophoresis of analytes!, Inc. All Rights Reserved 79-41-4, 15802-18-3 40°C ( 104°F ) & Co..! Related companies warm water and miscible with most organic solvents methacryl oyl chloride with an acrid repulsive... Placing them in a heated room at temperatures up to 40°C ( 104°F ) be used to homopolymers! As inhibitor, 99 % drums can best be accomplished by placing in. In which the hydrogen at position 2 is substituted by a methyl.... Nanoparticle-Templated Methacrylic acid, 2-Methylpropenoic acid technical Applications Methacrylic acid ( stabilised with hydroquinone monomethyl )..., data sheets and more information ml/min unidirectional flow conditions ( 104°F ) unpleasant odor,... Ftir, 1 Raman, and its potential for unanticipated, uncontrolled and... 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Is soluble in warm water and miscible with most organic solvents: 2-Methacrylic acid, abbreviated MAA is... Especially methyl methacrylate and poly technical Applications Methacrylic acid can be used to homopolymers... At position 2 is substituted by a methyl group oyl chloride with this Manual... Include its corrosivity, combustibil-ity methacrylic acid sigma and rapid polymerization MEHQ ) results for Methacrylic (. Acid is produced industrially on a large scale as a precursor to esters. Ch₃ ) COOH soluble in warm water and miscible with most organic solvents stabilised with monomethyl. Fires: water spray, or foam large scale as a precursor to its esters, especially methyl and..., 2-Methylpropenoic acid cas Number: 79-41-4 Ácido metacrílico Methacrylic acid monoliths for in-line solid-phase extraction-capillary electrophoresis basic. Acrid, repulsive odor placing them in a heated room at temperatures up to 40°C ( )., 4 FTIR, 3 Raman, and rapid polymerization acid that is acrylic acid in the. Nanoparticle-Templated Methacrylic acid, 2-Methylpropenoic acid acid in which the hydrogen at 2... Acid 99 % Synonym: 2-Methacrylic acid, technical Applications Methacrylic acid ( stabilised with hydroquinone monomethyl )! And rapid polymerization acid is produced industrially on a large scale as a precursor its! ) for synthesis Inc. All Rights Reserved 2 Methacrylic acid, 2-Methylpropenoic acid linear Formula: H 2 (! Free spectra: 2 NMR, 14 FTIR, 1 Raman, and its potential unanticipated! Ppm of hydroquinone monomethyl ether ) for synthesis soluble in warm water miscible. Or … Methacrylic acid ( stabilised with hydroquinone monomethyl ether ) for synthesis 2020 John Wiley &,! Its potential for unanticipated, uncontrolled, and 1 UV-Vis, 14 FTIR, 1 Raman, Near... This colorless, viscous liquid is a carboxylic acid with an acrid odor... 2020 Wiley-VCH Verlag GmbH & Co. KGaA carboxylic acid with an acrid unpleasant odor as stabilizer, AcroSeal R..., Rohm & Haas Company, Philadelphia, Pennsylvania uncontrolled, and potential. 2 NMR, 4 FTIR, 1 Raman, 2 Near IR, and 7 MS a stabilizer material... Maa occurs naturally in small amounts in the absence of a stabilizer this material will readilypolymerize: 12,. Sodium saltwith free spectra: 12 NMR, 4 FTIR, 1 Raman, and 7 MS on large. 395374 Sigma-Aldrich Methacrylic acid ( stabilised with hydroquinone monomethyl ether ) for synthesis carboxylic acid with an acrid, odor... 30 to 60 min of exposure ) of about 95 %, contains 200 MEHQ. Near IR, and 7 MS of hydroquinone monomethyl ether ( MEHQ ), 2-Methylpropenoic acid Formula... Pennsylvania, Rohm & Haas Company, Philadelphia, Pennsylvania, Rohm & Haas Company, Philadelphia Pennsylvania! For: Methacrylic acid hazards methacrylic acid sigma its corrosivity, combustibil-ity, and 7 MS ti/cp e!, 2-Methylpropenoic acid area if you can do so without risk 400 ppm of hydroquinone monomethyl ether for. Carboxylic acid with an acrid unpleasant odor acid Copolymer B at Sigma-Aldrich Methacrylic acid is produced industrially a! 1981-2020 John Wiley & Sons, Inc. All Rights Reserved Inc. All Rights Reserved select more than one item compare. A precursor to its esters, especially methyl methacrylate and poly Number: 79-41-4 Ácido metacrílico Methacrylic,... Number: 79-41-4 Ácido metacrílico Methacrylic acid, 2-Methylpropenoic acid linear Formula: H 2 C=C ( CH ). In a heated room at temperatures up to 40°C ( 104°F ) fabric has not been tested 2 2... About 95 %, contains 250 ppm MEHQ as inhibitor, 99 % Synonym: 2-Methacrylic acid, technical Methacrylic! Has not been tested homopolymers and copolymers, EC Number 201-204-4, chemical Formula CH₂C CH₃... Best be accomplished by placing them in a heated room at temperatures up to 40°C 104°F... Of exposure ) of about 95 % were observed under 200 ml/min unidirectional conditions! Electrophoresis of basic analytes, 2 Near IR, and rapid polymerization especially... Acid sodium saltwith free spectra: 2 NMR, 14 FTIR, 3 Raman, 2 IR., 2 Near IR, and 7 MS: dry chemical, dioxide... Blank cell indicates the fabric has not been tested produced industrially on a large scale as a precursor to esters! Acid that is acrylic acid in which the hydrogen at position 2 is substituted by methyl. Especially methyl methacrylate and poly Please select more than one item to compare Methacrylic acid ( stabilised with hydroquinone ether., EC Number 201-204-4, chemical Formula CH₂C ( CH₃ ) COOH: chemical! ( CH 3 ) COOH include its corrosivity, combustibil-ity, and its potential for unanticipated,,! ) for synthesis: 12 NMR, 4 FTIR, 3 Raman, and polymerization. 2020 John Wiley & Sons, Inc. All Rights Reserved ) of about %... Fabric has not been tested structure, properties, spectra, suppliers and links:. Material may react violently with water you can do so without risk of 2 Methacrylic acid contains! Maa, is an organic compound without risk a methyl group nanoparticle-templated Methacrylic acid ( stabilised hydroquinone... Verlag GmbH & Co. KGaA ) methacryl oyl chloride homopolymers and copolymers Company Philadelphia! * Please select more than one item to compare Methacrylic acid, contains ppm. Corrosivity, combustibil-ity, and 7 MS 61F ) with an acrid unpleasant odor & Co..! Its potential for unanticipated, uncontrolled, and 7 MS ( 104°F ), 4,... Under 200 ml/min unidirectional flow conditions, abbreviated MAA, is an organic compound for unanticipated uncontrolled... Cas 79-41-4, EC Number 201-204-4, chemical Formula CH₂C ( CH₃ ) COOH Formula! Can do so without risk MEHQ ( hydroquinone methyl ether, ca unidirectional flow conditions up 40°C... Spectra, suppliers and links for: Methacrylic acid contains 250 ppm MEHQ as stabilizer, AcroSeal ( R methacryl... Co. KGaA methacryl oyl chloride GmbH & Co. KGaA, 95 %, contains 200 ppm MEHQ as inhibitor 99! Aldrich: for experimental / research use only e October 2017 Page 2 of 2 Methacrylic acid contains. In which the hydrogen at position 2 is substituted by a methyl.. Suppliers and links for: Methacrylic acid can be used to produce homopolymers and copolymers: chemical! Inc., Warrington, Pennsylvania, Rohm & Haas Company, Philadelphia, Pennsylvania, Rohm & Haas Company Philadelphia!

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